Now on the molecular scale: Electricmotors northwesternu nature
) over the bulky IPP unit from point I to II′. As a result, the path-determining energy difference along path R4 is 4.7 kcal molhigher than that along path R3. These results indicate that, under reducing conditions, the CBPQTThe X-ray single-crystal structure of the reduced [3]catenaneunits in the loop. To study the unidirectional movement of the CBPQTrings under oxidizing condition, point II was set to be the starting point.
Four paths that all start at point II in two different directions were examined . Among the four paths, path O1 has the lowest energy barrier for the CBPQTrings encircle the T and BPM units. In path O1, the CBPQTring A to the T unit, so as to lower the overall energy. By comparison, in path O2, the CBPQTunit to its final location at the T unit, followed by moving the CBPQThigher than that along path O1.
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