Throughout the course of the MCU, there have been notable villains who were inadvertently created by Earth's Mightiest Heroes themselves.
Over the course of the MCU, there have been a handful of villains who were inadvertently created by the Avengers. Whether it was through negligence or the result of doing good with unintended consequences, there are notable instances in which Earth's Mightiest Heroes had to defeat the very threats they unintentionally made themselves. As such, the Avengers have left quite the legacy, notably saving the world on more than one occasion while also being responsible for a number of its foes.
9 Aldrich Killian Continuing the theme of Iron Man's sins coming back to haunt him, Aldrich Killian was rejected by Tony Stark years before he'd become Iron Man. As such, 2013's Iron Man 3 saw Killian's think tank known as AIM having developed Extremis, a nanotechnology to manipulate the body's bioelectricity.
Although Wanda released the town, the Scarlet Witch's studies of the Darkhold saw her becoming a villain in Doctor Strange in the Multiverse of Madness. As such, much of her darkness was instigated by the Avengers' initial failures and shortcomings. This is also combined with the fact that she was seemingly left to mourn Vision alone after Endgame which directly led to the incident in Westview.
5 Zemo The threat of Baron Zemo was a direct response to the lives lost during the Battle of Sokovia. Having lost his family, Zemo created a revenge plot against the Avengers using the Winter Soldier and his dark past as a potent weapon. In the face of the United Nations wanting to put regulations around Earth's Mightiest Heroes, Zemo took advantage of the tensions and successfully divided the Avengers by the end of 2016's Captain America: Civil War.
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