Achieving large and uniform particle sizes

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Achieving large and uniform particle sizes
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Dispersions of polymer particles in a liquid phase (latexes) have many important applications in coatings technology, medical imaging, and cell biology. A team of researchers has now developed a method to produce stable polystyrene dispersions with unprecedentedly large, and uniform, particle sizes.

Narrow size distributions are essential in many advanced technologies, but were previously difficult to produce photochemically.Dispersions of polymer particles in a liquid phase have many important applications in coatings technology, medical imaging, and cell biology. A French team of researchers have now developed a method, reported in the journalto produce stable polystyrene dispersions with unprecedentedly large, and uniform, particle sizes.

To obtain an external control over the process, the teams Muriel Lansalot, Emmanuel Lacôte, and Elodie Bourgeat-Lami at the Université Lyon 1, France, and colleagues, have turned to light-driven processes."Light-driven polymerization ensures temporal control, because polymerization proceeds only in the presence of light, whereas thermal methods can be started but not stopped once they are underway," Lacôte says.

The researchers therefore developed a fine-tuned chemical initiation system that responds to standard LED light in the visible range. This polymerization system, which is based on an acridine dye, stabilizers, and a borane compound, was the first to overcome the"300-nanometer ceiling," the size limit of UV and blue-light-driven polymerization in a dispersed medium.

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